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| Peltier
Effect (TEC) |
Seebeck
Effect (TEG) |
Piezo
Electric Effect |
NiTiNOL
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| Thermoelectrics
is the science and technology associated with thermoelectric converters,
that is, the generation of electrical power by the Seebeck effect and refrigeration
by the Peltier effect.
Thermoelectric generators
are being used in increasing numbers to provide electrical power in medical,
military, and deep space applications where combinations of their desirable
properties outweigh their relatively high cost and low generating efficiency.
In recent years there also has been an increase in the requirement for
thermoelectric coolers (Peltier devices) for use in infrared detectors
and in optical communications. |
Piezo
Electrics
Piezo Electric devices
as Motor/Generators, Infrared detectors, Acoustic Detectors, Generators
Applications:
Ultrasonic cleaning,
Sonar, Stereo speakers, Accelerometers, Micro positioners, Motion detectors,
Buzzers, Alarms, Microphones, Gas igniters, |
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Peltier Effect
ThermoElectric
Cooler
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Thermoelectric Materials:
Bismuth Telluride,
Antimony Telluride,
and Their Solid Solutions |
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TEC Schematic showing Hot side/Cold side Relationship
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TEC Plot Showing Optimum Power Input to Cooling Efficiency
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Seebeck Effect
ThermoElectric
Generator
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Thermoelectric Materials:
Bismuth Telluride,
Antimony Telluride,
and Their Solid Solutions |
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Delta Temperature in Electric power Out
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Piezo Electric Effect
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Piezo Bender |
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| The
Piezo Electric Effect was first discovered in 1880 by Pierre and Jacques
Curie. Some of the materiels they found Piezo properties in were crystals
of tourmaline, quartz, topaz, cane sugar and Rochelle salts.
Applications:
Piezoceramic signal filters, from simple ceramic resonators to selective
I.F. bandpass filters to very efficient SAW filters used as R.F. preselect
filtering for applications in television, radio, and communications equipment;
and piezoceramic igniters for natural gas/butane appliances; audio buzzers
(smoke alarms), air ultrasonic transducers used in intrusion alarms, auto
focus cameras, electronic 'tape measure.'
Ultrasonic cleaning,
Sonar, Stereo speakers, Accelerometers, Micro positioners, Motion detectors,
Buzzers, Alarms, Microphones, Gas igniters,
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Nitinol
Memory Wire
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Introduction to Shape
Memory and Superelasticity
Shape Memory Alloys, such as Nickel Titanium, undergo a phase transformation
in their crystal structure when cooled from the stronger, high temperature
form (Austenite) to
the weaker, low temperature form (Martensite). This inherent phase
transformation is the basis for the unique properties of these alloys --
in particular, Shape Memory and
Superelasticity.
Shape Memory
When a shape memory alloy is in its martensitic form, it is easily deformed
to a new shape. However, when the alloy is heated through its transformation
temperatures, it
reverts to austenite and recovers its previous shape with great force.
This process is known as Shape Memory.
The temperature at which the alloy remembers its high temperature form
when heated can be adjusted by slight changes in alloy composition and
through heat treatment. In
the Nickel Titanium alloys, for instance, it can be changed from above
+100 deg.C to below -100 deg.C. The shape recovery process occurs over
a range of just a few
degrees and the start or finish of the transformation can be controlled
to within a degree or two if necessary.

Schematic of the Shape Memory Effect
Superelasticity
These unique alloys also show a Superelastic behavior if deformed at
a temperature which is slightly above their transformation temperatures.
This effect is caused by the
stress-induced formation of some martensite above its normal temperature.
Because it has been formed above its normal temperature, the martensite
reverts immediately to
undeformed austenite as soon as the stress is removed. This process
provides a very springy, "rubberlike" elasticity in these alloys.

Typical Loading and Unloading Behavior of Superelastic NiTi
Typical Properties of NiTi Shape Memory Alloys
Martensite is...
Fairly Weak: 10,000 to 20,000
psi deformation stress
Able to absorb up to 8% recoverable
strain
Austenite is...
Strong: 35,000 to 100,000
psi yield strength
Both forms of the alloy are...
Ductile: elongation to failure
over 25%
Strong: tensile strength
up to 200,000 psi
Biocompatible and extremely
corrosion resistant |
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